Use The Following Mo Diagram To Find The Bond Order For O2
From that diagram you can then easily fill out what the o2 and o2 mo diagrams should beand that is in the second photo i included. Chemical bonding and molecular structure.
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Molecular orbital diagram for oxygen gas o2.
Use the following mo diagram to find the bond order for o2. For each of the species c2 o 2 f 2 and no a write the molecular orbital diagram as in exampleexample bdetermine the bond order and state whether you expect the species to be stable or unstablec determine if the species is diamagnetic or paramagnetic. In molecular orbital theory bond order is also defined as half of the difference between the number of bonding and antibonding electrons. And if paramagnetic indicate the number of unpaired electrons.
For a straightforward answer. Fill from the bottom up with 12 electrons total. Bond order number of electrons in bonding molecules number of electrons in antibonding molecules2.
Molecular orbitals mo are constructed from atomic orbitals. It is sigma2s2sigma2s2sigma2p2pi2p4pi2p4 bond order 1. Compare the stabilities of o2 o2 o22.
Thus decreasing order of. Information from the mo diagram justify o2s stability and show that its bonding order is 2. The first photo is straight from a 2006 edition pearson general chemistry textbook and it shows you what the molecular orbital mo diagram for o2 is.
With the increase in number of electrons in anti bonding orbital the stability and bond order of the molecule decreases. In fact its the perioxide ion. Bonding order is 2 and it is paramagnetic.
The stabilities of these can be best explained using molecular orbital theory. In o 2 and f 2 there is a crossover of the sigma and the pi ortbials. The relative energies of the sigma orbitals drop below that of the pi orbitals.
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